Atletico Madrid had Luis Suarez in its side but was held to its second 0-0 draw in a week as the team failed to break down Villarreal with just two shots on target in the entire 90 minutes.
Universidad Catolica midfielder Jose Carabali also earned his first national call-up for the matches in Buenos Aires on October 8 and Quito five days later.
The South American zone's 2022 World Cup qualifiers had been scheduled to begin in late March but were postponed because of the coronavirus pandemic.
Julian Draxler, Idrissa Gueye and Kylian Mbappe added another three in the second half while Angers pulled one back in the 52nd minute.
Earlier on Friday, Jiangsu defeated Shanghai 3-0 (25-17, 25-20, 26-24) in the third-place match.
More than 100 cyclists from bicycle clubs and associations around China have signed up for the three-day event, organizers said.
Jiangsu's 8-0 run to start the game forced Tianjin into an early timeout. Tianjin lost too many defensive rebounds to provide their opponents with second chance baskets, digging a 29-7 hole for themselves after the first quarter.
Liverpool's defense was overrun for the entire 90 minutes at Villa Park with Ollie Watkins scoring a first half hat-trick, Jack Grealish scoring twice and John McGinn and, new arrival, Ross Barkley also getting in on the act.
"I mean, we both gave everything," said the third-seeded Thiem. "The thing in tennis is that there is one loser, one winner. Despite (being) so disappointed, I'm still happy for him."
The appointment of Waldrum by the Nigeria Football Federation (NFF) came a year after Swede Thomas Dennerby resigned from the job in October 2019.
The 30-year-old, who has been capped once for Argentina's national team, has struggled for opportunities since joining Boca from Mexico's Cruz Azul in January 2019.